Spectroscopy of Nanostructures

Our group specializes in many different optical spectroscopy techniques, such as time-resolved optical spectroscopy (in a very broad range, from nanoseconds up to miliseconds) or micro-Raman scattering spectroscopy (down to ultra-low acoustic frequencies). We use these methods to study various optical phenomena occurring in colloidal nanostructures synthetized in our lab. Broadly speaking, our interest lies in understanding and controlling light emission and absorption processes in such nanostructures as well as their vibrational dynamics. Besides fundamental science, this knowledge allows us to design better materials and to optimise production processes.

Photoluminescence decays
Non-single exponential photoluminescence decays of hydrogenated and non-hydrogenated Tb-nanoclusters and change of their fractal dimension deduced from ion-ion interactions.
Left: Two-dimensional photoluminescence excitation maps of GaN:Eu3+ nanocrystals.
Right: Ultra-low frequency Raman spectra of silicon nanocrystals with different sizes, measured at different polarization geometries. These spectra show that acoustic phonons confined in silicon nanocrystals have size-dependent energies and different symmetries. [Phys. Rev. B. , 91, 235444 (2015)]
FTIR absorbance spectra measured for (a) Tb:SiNx film annealed at 1100 °C shortly after deposition process (b) Tb:SiNx film annealed at 1100C measured after storage in ambient atmosphere for one year (c) SiOxNy film (22.42 at. % Si, 13.410 at. % N and 41.120 at. % O). Spectra (b) and (c) were used for the purpose of FTIR absorbance discussion. Dashed arrow represents the shift of Si-N absorbance peak and is only a guide to the eye. The spectra were vertically shifted for clarity. [Thin Solid Films, 675, 5 (2019)]